http://www.wiringdiagrams21.com/2009/11/28/a-typical-crowbar-circuit-diagram
Hi, I plan to alter the circuit to include two 200 volt zener diodes in series to replace ZD1. I am not sure if the zeners will brake down at 400 volts.
This circuit is indeed simple and generally fairly reliable. However a couple of things I'd just like to point out.
Zener diodes don't have a particularly sharp knee, so as long as you're not too concerned about the exact voltage it triggers at, you're fine.
The other thing I'd be slightly concerned about is that if your diodes break down (and putting 400V DC into a circuit like that is a fairly taxing environment), then you have the potential for a LOT of magic smoke.
A few things, in no particular order. The SCR doesn't need much gate current to trigger, so I'd put a fairly high value resistor in series with the zeners, on the "hot" side as a safety device. The 1K resistor will (obviously) need some careful calculation. Remember to calculate things like: how much current will flow if you get (say) 450V, if the zeners will survive it and how much power that resistor will need to dissipate.
If you want are more precise control of your voltage, rather than the crude-but-effective zener triggered crowbar, consider using an opamp or comparator. With a suitable divider (eg, 470K top, 6K8 on the bottom) 400V DC in would give you 5.7V on the tap. Thats easily in a safe and comfortable range for a simple comparator (eg, LM311). With its gain, you will have quite accurate and repeatable trigger points, and a nice sharp turn-on to drive your optocoupler.